Oxidation Studies with Peroxomonophosphoric Acid. III. A Kinetic and Mechanistic Study of Oxidation of Dialkyl Sulfides
نویسندگان
چکیده
منابع مشابه
Bioinorganic Hydrocarbon Oxidation : Mechanistic and Kinetic Studies
Chapter 1. Principles of Small Molecule Activation by Metalloproteins as Exemplified by the Soluble Methane Monooxygenase Many metalloenzymes activate small molecules in a manner that is unique to natural systems. In this perspective we discuss the soluble protein system from Methylococcus capsulatus (Bath), which uses a mixed-function hydroxylase to convert methane selectively to methanol. Thr...
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برهمکنش dnaتیموس گاوی طبیعی (ct-dna) با اتیلن دی آمین تترااستات (edta)در بافرtris-hcl با 8/7 ph ( دراین ph،edta به نمک دی سدیم تبدیل می شود) وسسامول در بافر tris-hcl با4/7 ph مورد بررسی قرار گرفته است. edta و سسامول استفاده فراوانی در تکنولوژی غذایی و صنعت شیمیایی دارند. مدل اتصال dna مربوط بهedta بوسیله اسپکتروفتومتری جذب، دورنگ نمایی حلقوی(cd)، ویسکومتری وژل الکتروفورز بررسی شده است. طیفuv ...
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متن کاملChromic Acid Oxidation of Methylaminopyrazole Formamidine in Sulfuric Acid Medium: A Kinetic and Mechanistic Approach
The kinetics of chromic acid oxidation of one of aminopyrazole formamidine derivatives, namely N,N-dimethylN’-(5-methyl-1H-pyrazol-3-yl) formamidine (MAPF)in sulfuric acid solutions has been investigated at constant ionic strength and temperature. The progress of the reaction was followed spectrophotometrically. The reaction showed a first order dependence on [chromic acid] and fractional-first...
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ژورنال
عنوان ژورنال: Bulletin of the Chemical Society of Japan
سال: 1980
ISSN: 0009-2673,1348-0634
DOI: 10.1246/bcsj.53.2366